Secondary metabolites, structure diagram: Trivial name – aspochalasin A

Date: 26 November 2013

Secondary metabolites, structure diagram: Trivial name – aspochalasin A

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Notes:

Species: A. microcysticusSystematic name: 1H-Cycloundec[d]isoindole-1,15(2H)-dione, 3,3a,4,6a,9,10,11,12-octahydro-11,12-dihydroxy-4,5,8-trimethyl-3-(2-methylpropyl)-, (3S,3aR,4S,6aS,7E,11S,12S,13E,15aS)-Molecular formulae: C24H33NO4Molecular weight: 401Chemical abstracts number: 71968-02-0Selected references: Keller-Schierlein, Walter; Kupfer, Ernst (Org. Chem. Lab., ETH, Zurich CH-8092, Switz.). Helv. Chim. Acta, 62(5), 1501-24 (German) 1979.Toxicity Toxicity unknown

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Immune reconstitution syndrome (mucous impaction or obstructing bronchial aspergillosis) complicating pulmonary aspergillosis in AIDS.

Chest X ray (+64 days)
Immune reconstitution syndrome (mucous impaction or obstructing bronchial aspergillosis) complicating pulmonary aspergillosis in AIDS.

Chest X ray (+day 42)
Immune reconstitution syndrome (mucous impaction or obstructing bronchial aspergillosis) complicating pulmonary aspergillosis in AIDS

Chest X ray (+day 14)
Orbital aspergillosis with late fungemia
Chronic fibrosing pulmonary aspergillosis

Chronic fibrosing pulmonary aspergillosis pt RS.
Pleural thickening followed by CNPA

Image G. 14/5/99
Showing progression of the cavity with some debris inside
Pleural thickening followed by CNPA

Image F. 14/5/99
Compare with B, showing progressive enlargement of cavity and formation of fungal ball.
Pleural thickening followed by CNPA

Image E 14/5/99
Showing enlargement of cavity at left apex and formation of a new cavity there.
Pleural thickening followed by CNPA

Image D 30/3/99
One medium sized irregular cavity at left apex
Pleural thickening followed by CNPA

Image C. 30/3/99
Parenchymal or pleural disease adjacent to the mediasternum on the left with diffuse parenchymal disease. Also pleural based nodules bilaterally.