Dehydroaustin

ID 2: 148

Toxin: n

Trivial name: Austin, 19,​34-​didehydro-​12-​deoxy-​12,​18-​epoxy-​18,​19-​dihydro-​, (18β)​-; Dehydroaustin

Systematic name:

Spiro[1H,4H,8H-3a,7a-epoxy-6,11b-methano-3H-furo[3,4-e][3]benzoxocin-9(10H),3′(6’H)-[2H]pyran]-1,4,6′-trione, 7-(acetyloxy)-6,7,11,11a-tetrahydro-2′,2′,3,6,11a-pentamethyl-8,12-bis(methylene)-, (3R,3’R,3aR,6S,7R,7aR,11aR,11bS)-

Molecular formulae: 

C27H30O9

Molecular weight: 498.52

Chemical abstract number: 82893-35-4

Literature reference:

  • Studies on fungal metabolites. Part 3. Carbon-​13 NMR spectral and structural studies on austin and new related meroterpenoids from Aspergillus ustus, Aspergillus variecolor, and Penicillium diversum. Simpson, Thomas J.; Stenzel, Desmond J.; Bartlett, Alan J.; O’Brien, Eugene; Holker, John S. E. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) (1982), (11), 2687-92.
    Structure of ED-​1 isolated from Emericella dentata. Maebayashi, Yukio; Okuyama, Emi; Yamazaki, Mikio; Katsube, Yukiteru. Chemical & Pharmaceutical Bulletin (1982), 30(5), 1911-12.

References URL: 

Aspergillus Species known to produce this metabolite:

Toxicity:

Convulsive

Structure image:  

dehydroaustinweb

Date uploaded: 2008-07-07 16:08:30


Mycotoxin & Metabolites

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