Dithiosilvatin

Toxin: 

n

Trivial name: 

2,​3-​Dithia-​5,​7-​diazabicyclo[2.2.2]​octane-​6,​8-​dione, 5,​7-​dimethyl-​1-​[[4-​[(3-​methyl-​2-​butenyl)​oxy]​phenyl]​methyl]​-​, (1R)​-; 2,​3-​Dithia-​5,​7-​diazabicyclo[2.2.2]​octane-​6,​8-​dione, 5,​7-​dimethyl-​1-​[[4-​[(3-​methyl-​2-​butenyl)​oxy]​phenyl]​methyl]​-​, (1R,​4R)​- (9CI); Dithiosilvatin; Dithiosilvatine

Systematic name: 

2,​3-​Dithia-​5,​7-​diazabicyclo[2.2.2]​octane-​6,​8-​dione, 5,​7-​dimethyl-​1-​[[4-​[(3-​methyl-​2-​buten-​1-​yl)​oxy]​phenyl]​methyl]​-​, (1R,​4R)​-

Molecular formulae: 

C18 H22 N2 O3 S2

Molecular weight: 

378.51

Chem abstract number: 

112269-38-2

Literature reference: 

Studies on fungal products. Part 13. Isolation and structures of dithiosilvatin and silvatione, novel dioxopiperazine derivatives from Aspergillus silvaticus. Kawahara, Nobuo; Nozawa, Koohei; Nakajima, Shoichi; Kawai, Kenichi. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) (1987), (9), 2099-101

Structure image: 

Aspergillus Species known to produce this metabolite: 

3d image file .c3d (requires Chem3d http://www.cambridgesoft.com/Ensemble_for_Chemistry/ChemBio3D/): 

jmol file (.mol) requires Java to run (http://www.java.com/en/download/help/enable_panel.xml): 


Date uploaded: 

2008-07-07 16:08:30